Crystal structure of YbMn∼0.17Si∼1.83: a new AlB2–BaAl4 intergrowth compound
Identifieur interne : 002733 ( Main/Exploration ); précédent : 002732; suivant : 002734Crystal structure of YbMn∼0.17Si∼1.83: a new AlB2–BaAl4 intergrowth compound
Auteurs : N. M Norlidah [France] ; I. Ijjaali [France] ; Gérard Venturini (physicien) [France] ; B. Malaman [France]Source :
- Journal of Alloys and Compounds [ 0925-8388 ] ; 1998.
Descripteurs français
- Wicri :
- topic : Collecte de données.
English descriptors
- KwdEn :
- Alloys comp, Atomic coordinates, Atomic percentage, Baal, Binary erge, Cenisi, Coge, Compound, Crystal structure, Crystallographic data, Data collection, Earth elements, Elsevier science, Erge, Erge compound, Interatomic distances, Local order, Manganese atoms, Many cenisi, Microprobe analysis, Norlidah, Occupancy factors, Prism, Propagating vector, Rare earth, Residual factor, Silicide, Silicon, Silicon atoms, Structural evolution, Structural relationships, Sublattice, Ternary compounds, Thermal parameters, Trigonal prisms, Type compounds, Type structure, Type structure compounds, Type structures, Ybmn.
- Teeft :
- Alloys comp, Atomic coordinates, Atomic percentage, Baal, Binary erge, Cenisi, Coge, Compound, Crystal structure, Crystallographic data, Data collection, Earth elements, Elsevier science, Erge, Erge compound, Interatomic distances, Local order, Manganese atoms, Many cenisi, Microprobe analysis, Norlidah, Occupancy factors, Prism, Propagating vector, Rare earth, Residual factor, Silicide, Silicon, Silicon atoms, Structural evolution, Structural relationships, Sublattice, Ternary compounds, Thermal parameters, Trigonal prisms, Type compounds, Type structure, Type structure compounds, Type structures, Ybmn.
Abstract
Abstract: We report on the crystal structure of YbMn0.17Si1.83, a new type structure based on an intergrowth of three AlB2 blocks and one BaAl4 block. In the BaAl4 block, the manganese atoms occupy one third of the pyramidal sites as observed in many non-stoichiometric CeNiSi2-type compounds. The inner AlB2 block is only 2/3 occupied by the silicon atoms as observed in the related Ho3Si4 and ErGe1.83 compounds. Isotypic and related compounds are found in other R–Mn–Si systems (R=Ho–Lu). The structural relationships with other binary and ternary compounds are examined and the common structural features are discussed.
Url:
DOI: 10.1016/S0925-8388(98)00618-5
Affiliations:
- France
- Grand Est, Lorraine (région)
- Nancy, Vandoeuvre les Nancy
- Centre national de la recherche scientifique, Institut Jean Lamour, Université de Lorraine
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Le document en format XML
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<front><div type="abstract" xml:lang="en">Abstract: We report on the crystal structure of YbMn0.17Si1.83, a new type structure based on an intergrowth of three AlB2 blocks and one BaAl4 block. In the BaAl4 block, the manganese atoms occupy one third of the pyramidal sites as observed in many non-stoichiometric CeNiSi2-type compounds. The inner AlB2 block is only 2/3 occupied by the silicon atoms as observed in the related Ho3Si4 and ErGe1.83 compounds. Isotypic and related compounds are found in other R–Mn–Si systems (R=Ho–Lu). The structural relationships with other binary and ternary compounds are examined and the common structural features are discussed.</div>
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